no benzene plasticizer epoxidized fatty acid methyl esters epoxidized soybean oil acrylated partly replace the primary plasticizer

 
plasticizers derived from biomass resources: a short review

Plasticizers Derived from Biomass Resources: A Short Review

Currently, vegetable oils and epoxidized fatty acid esters have been used on the market [13,14]. Epoxidized soybean oil (ESO) is a collection of organic compounds obtained from the epoxidation of soybean oil that have been widely used as plasticizers and heat stabilizers of PVC materials. The chemical structure of ESO is shown in Figure 1.

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transesterification of epoxidized soybean oil to prepare ...

Transesterification of epoxidized soybean oil to prepare ...

The transesterification was complete in 10min at 50◦C without loss of the epoxide. function. Epoxidized methyl esters represent a renewable substrate that is readily con-. verted into surfactants, fuel additives, and other industrial products.

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epoxidized soybean oil (eso) , epoxy fatty acid

Epoxidized Soybean Oil (ESO) , Epoxy Fatty Acid

Hebei plasticizers co., LTD. (formerly hebei jingu grease technology co., LTD.) is the branch of hebei jingu group, now has Epoxy fatty acid methyl ester (100,000 tons ),epoxidized soybean oil (60,000 tons),Methyl Oleate (100,000tons),etc .Our Epoxy Fatty Acid Methyl Ester(EFAME) Epoxidized Soybean Oil(ESO) are new eco-friendly and nontoxic PVC plasticizers, mainly replace benzene and adjacent ...

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epoxidized soybean oil acrylated non toxic plasticizer ...

Epoxidized Soybean Oil Acrylated Non Toxic Plasticizer ...

Epoxidized Soybean Oil Acrylated Non Toxic Plasticizer Efame Suitable To Replace Dop Primary Plasticizer In Pvc , Find Complete Details about Epoxidized Soybean Oil Acrylated Non Toxic Plasticizer Efame Suitable To Replace Dop Primary Plasticizer In Pvc,Epoxidized Soybean Oil Acrylated,Dop,Plasticizer from Leather Auxiliary Agents Supplier or Manufacturer-Hebei Jingu Plasticizer Co., Ltd.

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epoxidized fatty acid methyl esters epoxidized soybean oil ...

Epoxidized Fatty Acid Methyl Esters Epoxidized Soybean Oil ...

Epoxidized Fatty Acid Methyl Esters Epoxidized Soybean Oil Acrylated Partly Replace The Primary Plasticizer , Find Complete Details about Epoxidized Fatty Acid Methyl Esters Epoxidized Soybean Oil Acrylated Partly Replace The Primary Plasticizer,Non Phthalate Plasticizer,Plasticizer,Epoxidized Soybean Oil Acrylated from Leather Auxiliary Agents Supplier or Manufacturer-Hebei Jingu Plasticizer ...

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wo2014061026a1 - epoxidized fatty acid alkyl ester ...

WO2014061026A1 - Epoxidized fatty acid alkyl ester ...

Epoxidized fatty acid alkyl ester and methods for making epoxidized fatty acid alkyl ester. The epoxidized fatty acid alkyl ester is prepared from a fatty acid alkyl ester starting material comprising at least one of mono-unsaturated and di-unsaturated fatty acid alkyl ester molecules in a combined amount of at least 85 weight percent.

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effects of different epoxidation methods of soybean oil on ...

Effects of different epoxidation methods of soybean oil on ...

cal polymerization [1–12]. Epoxidized soybean oil (ESO) has been produced for the last 30years and is available under various trade names. ESO has 910 Effects of different epoxidation methods of soybean oil on the characteristics of acrylated epoxidized soybean oil-co-poly(methyl methacrylate) copolymer

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thermal stability of poly(vinyl chloride) with epoxidised ...

Thermal stability of poly(vinyl chloride) with epoxidised ...

The hydrogenated castor oil is a mixture of glycerin acetates and acetic acid esters of mono- and diglycerides of fatty acids while epoxidized soybean oil is a plasticizer employed in toy and ...

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mechanical and rheological properties of epoxidized ...

Mechanical and Rheological Properties of Epoxidized ...

Mechanical and Rheological Properties of Epoxidized Soybean Oil Plasticized Poly(lactic acid) Article in Journal of Applied Polymer Science 112(6):3185-3191 · June 2009 with 179 Reads

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cn104718248a - epoxidized fatty acid alkyl ester ...

CN104718248A - Epoxidized fatty acid alkyl ester ...

The invention relates to an epoxidized fatty acid alkyl ester and methods for making epoxidized fatty acid alkyl ester. The epoxidized fatty acid alkyl ester is prepared from a fatty acid alkyl ester starting material comprising at least one of mono-unsaturated and di-unsaturated fatty acid alkyl ester molecules in a combined amount of at least 85 weight percent.

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soybean oil-based thermosets with n-vinyl-2-pyrrolidone

Soybean oil-based thermosets with N-vinyl-2-pyrrolidone

Soybean oil-based thermosets from acrylated epoxidized soybean oil (AESO) with a highly reactive vinyl monomer, N-vinyl-2-pyrrolidone (NVP), as crosslinking agent to replace styrene (St) were formulated for the fabrication of hemp fiber composites.The theoretical miscibility of NVP–AESO and St–AESO systems were discussed based on the group contribution method.

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epoxidized linolenic acid salts as multifunctional ...

Epoxidized linolenic acid salts as multifunctional ...

The EFAE utilized were epoxidized soybean oil (ESO) and epoxidized fatty acid methyl ester (e-FAME). All plasticizers were compatible with PVC, with plasticization efficiencies usually increasing ...

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1. introduction

1. Introduction

Acrylated soybean oil has been used extensively in the area of surface coatings and is commercially manufactured in forms such as EBECRYL 860 (UCB Chemical Company). Epoxidized soybean oil and epoxidized linseed oil are predominantly used as an alternative plasticizer and stabilizer in PVC in place of phthalates.

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plasticizer epoxy fatty acid methyl ester to partly ...

Plasticizer Epoxy Fatty Acid Methyl Ester To Partly ...

Plasticizer Epoxy Fatty Acid Methyl Ester To Partly Replace Dotp Bio Plasticizer To Help The Environment , Find Complete Details about Plasticizer Epoxy Fatty Acid Methyl Ester To Partly Replace Dotp Bio Plasticizer To Help The Environment,Epoxidized Soybean Oil Acrylated,Plasticizer,Dotp from Leather Auxiliary Agents Supplier or Manufacturer-Hebei Jingu Plasticizer Co., Ltd.

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synthesis and performance of surfactants

Synthesis and performance of surfactants

Synthesis and performance of surfactants based on epoxidized methyl oleate and glycerol Article in Journal of Surfactants and Detergents 9(4):377-383 · December 2006 with 135 Reads

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edible grade plasticizer big factory supply epoxidized ...

Edible grade plasticizer Big factory supply Epoxidized ...

Epoxidized soybean oil. Epoxidized soybean oil (ESBO) is a collection of organic compounds obtained from the epoxidation of soybean oil. It is used as a plasticizer and stabilizer in polyvinyl chloride (PVC) plastics. ESBO is a yellowish viscous liquid.

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thermal degradation and flame retardant mechanism of poly ...

Thermal degradation and flame retardant mechanism of poly ...

Epoxidized soybean oil has been used as plasticizer of PVC for years, but the synthesis of soybean oil including flame retardant groups and the mechanism of flame retardant has never been reported. In this work, we prepared a novel bio-based plasticizer containing retardant groups based on soybean oil, and partly to replace the phthalate as ...

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design and synthesis of ethoxylated esters derived

Design and synthesis of ethoxylated esters derived

Zheng et al. (2018) also observed the epoxidized WCO-based methyl ester could partly replace toxic dioctyl phthalate. However, the former needs rigorous treatment condition (under 250 °C, vacuum distillation) to obtain intermediate fatty acid methyl ester, while the later one can only be used as a secondary plasticizer.

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ep2070977a2 - epoxidised vegetable oils as pvc ...

EP2070977A2 - Epoxidised vegetable oils as PVC ...

The present descriptive report refers to a patent of invention of PVC plasticizers composed of epoxidized bioesters of vegetable oil fatty acids obtained by partial transesterification with ethanol and glycerin and further acetylation and epoxidation, and PVC compounds plasticized with bioesters resulting from partial transesterification, acetylation and epoxidation, belonging to the technical ...

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bamboo fibers composites based on styrene-free soybean-oil ...

Bamboo fibers composites based on styrene-free soybean-oil ...

To facilitate the formulation of acrylated epoxidized soybean oil (AESO) resins with a low viscosity and high crosslinking density, two methacrylate monomers, i.e., 1,4-butanediol dimethacrylate (BDDMA) and trimethylolpropane trimethacrylate (TMPTMA) were respectively used as reactive diluents (RDs) for replacing anticipatory carcinogenic styrene.

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bio-based textile coatings and composites - sciencedirect

Bio-based textile coatings and composites - ScienceDirect

The majority of epoxidized fatty acid esters are compatible with PVC and the efficiency decreases with increasing molecular weight (Chaudhary et al., 2015). Ester-amides of ricinoleic acid are evaluated as plasticizer in PVC. The glass transition temperature of PVC blends containing up to 40 wt% of the plasticizer decreased down to −13.5°C.

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green approaches to engineer tough biobased epoxies: a ...

Green Approaches To Engineer Tough Biobased Epoxies: A ...

The next approach implemented by the group(105,107,108) was prepolymerization of epoxidized soybean oil or vernonia oil and preparing biobased rubber. One phase interpenetrated network (IPN), two-phase IPN or phase inverted IPN was observed depending on the content of epoxidized vegetable oil (EVO) and type of curing agent.

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us20090149585a1 - primary pvc plasticizers derived

US20090149585A1 - Primary pvc plasticizers derived

The present descriptive report refers to a patent of invention of PVC plasticizers composed of epoxidized bioesters of vegetable oil fatty acids obtained by partial transesterification with ethanol and glycerin and further acetylation and epoxidation, and PVC compounds plasticized with bioesters resulting from partial transesterification, acetylation and epoxidation, belonging to the technical ...

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catalytic approaches to monomers for polymers based on ...

Catalytic Approaches to Monomers for Polymers Based on ...

Polymers are used in simple consumer items like carpets, furniture, glues, and clothing but are also used in advanced engineering, including materials used in the aerospace industry. Therefore, polymers and consequently their monomers play an important role in our everyday life. Currently, most of the monomers are produced from fossil resources, the supply of which is diminishing. In this ...

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modified vegetable oil based additives as a future ...

Modified Vegetable Oil Based Additives as a Future ...

Acrylated soybean oil has been used extensively in the area of surface coatings and is commercially manufactured in forms such as EBECRYL 860 (UCB Chemical Company). Epoxidized soybean oil and epoxidized linseed oil are predominantly used as an alternative plasticizer and stabilizer in PVC in place of phthalates.

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preparation and properties of polyether aliphatic ...

Preparation and Properties of Polyether Aliphatic ...

We also used epoxy fatty acid methyl ester (EFAME) to prepare an epoxy curing agent. EFAME contains multiple active epoxy groups and is derived from vegetable oil. EFAME is a renewable plasticizer, compatibilizer, dispersing agent, surfactant, and softener due to its sustainable production and reasonable costs.

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us20090149585a1 - primary pvc plasticizers derived

US20090149585A1 - Primary pvc plasticizers derived

The present descriptive report refers to a patent of invention of PVC plasticizers composed of epoxidized bioesters of vegetable oil fatty acids obtained by partial transesterification with ethanol and glycerin and further acetylation and epoxidation, and PVC compounds plasticized with bioesters resulting from partial transesterification, acetylation and epoxidation, belonging to the technical ...

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special issue: sustainable polymers and polymer science ...

Special Issue: Sustainable Polymers and Polymer Science ...

tion of acrylated fatty acid methyl esters as styrene replacements in triglyceride-based thermosets in 2009 to prepare nearly 100% bio-based resins.53 AESO and maleinated castor oil monoglycer-ide were used as bio-based crosslinkers and diluted with either styrene or an acrylated fatty acid methyl ester-based monomer.

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lubricants | free full-text | chemically modifying ...

Lubricants | Free Full-Text | Chemically Modifying ...

Schafer et al. described the development of corrosion-protection additives from an epoxidized methyl ester of an unsaturated fatty acid and a sulphonic acid . Rowland et al. disclosed different antifrictional additives from an epoxidized ester of fatty acids to reduce lead corrosion in lubricants and fuels .

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from monomers to polymers from renewable resources: recent ...

From monomers to polymers from renewable resources: Recent ...

Acrylated epoxidized soybean oil (AESO), synthesized from the reaction of acrylic acid with epoxidized soybean oil [164,165], is commercially available under the brand name Ebecryl 860 from the UCB Chemicals Company and has been extensively studied in polymers and composites, particularly as a photosensitive coating material [164,165].

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lightweight materials from biofibers and biopolymers - acs ...

Lightweight Materials from Biofibers and Biopolymers - ACS ...

Lightweight Materials from Biofibers and Biopolymers. Danning Zhang * 1 2 3. ... sunflowers, castors and olives consist of triglycerides structured of various fatty acids. The distribution of fatty acids varies in different vegetable species. ... such as acrylated epoxidized soybean oil (AESO). The new KFS lightwt. composites have a d. ρ ≈ 1 ...

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biobased thermosets - sciencedirect

Biobased Thermosets - ScienceDirect

Acrylated triglycerides can react via additional polymerization. Acrylated epoxidized soybean oil is commercially available for the surface coatings industry. The reaction of acrylic acid with epoxidized soybean oil occurs through a standard substitution, as can be seen schematically in Figure 15.5.

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