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The invention discloses a process of recycling terephthalic acid to produce DOTP (dioctyl terephthalate) by using polyester alkaline to reduce wastewater. The process comprises the following process steps: adding terephthalic acid reclaimed materials and isooctyl alcohol into a reaction kettle in a certain proportion, stirring and heating, adding a catalyst and activated carbon when water ...

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Synthesis of epoxy fatty acid methyl ester (EFAME) EFAME was synthesized by a two-step procedure of transesterification and epoxidation ( Evelyne et al., 2010 ; Feng et al., 2015a ; b ). The anhydrous waste cooking oil (100 g) and KOH CH 3 OH solution (0.5 g/18 g) were mixed in a flask with a mechanical stirrer and a condenser pipe.

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Zheng et al. (2018) also observed the epoxidized WCO-based methyl ester could partly replace toxic dioctyl phthalate. However, the former needs rigorous treatment condition (under 250 °C, vacuum distillation) to obtain intermediate fatty acid methyl ester, while the later one can only be used as a secondary plasticizer.

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Epoxidized fatty acid methyl esters are more soluble and often impart better flexibility to the plastic even at low temperatures. The saturated methyl esters fraction cannot be epoxidized and has a low affinity with the polymeric matrix, tending to migrate to the surface. Work has been done to improve the epoxide yield .

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